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21.
Rasoul Esmaeili Mohammad Ebrahimi Ji’En Zhang Zhiyong Zhang Yasser Abd El-Rahman 《International Geology Review》2020,62(13-14):1677-1697
ABSTRACT The Makran complex in southeast Iran provides a spectacular subduction-related accretionary complex to understand the mechanism of oceanic accretion and the evolution of subduction zones. In this paper, we present new major and trace element data as well as isotopic compositions of mafic volcanic blocks from the Makran ophiolitic mélange complex (OMC). Our aim is to assess the genesis of these rocks and discuss their implications on the evolution of Neotethys Ocean. These volcanic blocks are composed mainly of basalts with minor trachytes. The Makran lavas are occasionally interlayered with tuff layers. Zircons from these tuffs give U-Pb ages of 95 Ma, which is well in accordance with the reposted microfossil data for the interlayered pelagic limestones with pillow lavas. Makran basalts can be geochemically subdivided into four groups; normal to transitional MORB, enriched-MORB, Plume-type MORB and alkaline (-OIB-like) basalts. The OIB-like pillow lavas are represented by high values of Th/Tb (6.3–7.4) which are higher than other basalts (group 1 = 0.3–0.8; groups 2 = 0.7–1.6; group 3 = 1.58–1.36).143Nd/144Nd(t) ratios for basalts ranges from 0.51247 to 0.51292, whereas 87Sr/86Sr(t) isotopic composition of the OMC lavas varies from 0.704433 to 0.709466. The Pb isotopic composition of the lavas are quite high, ranging from 15.49–15.66 for 207Pb/204Pb(t), 18.09–19.12 for 206Pb/204Pb(t) and 37.80–39.23 for 208Pb/204Pb(t). The chemistry of these rocks suggests that they were formed most likely in an oceanic setting with clear plume-ridge interaction. These rocks can form from partial melting of a highly heterogeneous mantle source, which is extensively metasomatized with deep mantle OIB-type components. We suggest these rocks have been generated in an oceanic ridge with plume-ridge interaction, similar to the Iceland-Reykjanes Ridge, before being fragmented and accreted into the Makran accretionary complex. 相似文献
22.
Tomoki Sato Takashi Miyazaki Yoshihiko Tamura James B. Gill Martin Jutzeler Ryoko Senda Jun‐Ichi Kimura 《Island Arc》2020,29(1)
The International Ocean Discovery Program Expedition 350 drilled between two Izu rear‐arc seamount chains at Site U1437 and recovered the first complete succession of rear‐arc rocks. The drilling reached 1806.5 m below seafloor. In situ hyaloclastites, which had erupted before the rear‐arc seamounts came into existence at this site, were recovered in the deepest part of the hole (~15–16 Ma). Here it is found that the composition of the oldest rocks recovered does not have rear‐arc seamount chain geochemical signatures, but instead shows affinities with volcanic front or some of the extensional zone basalts between the present volcanic front and the rear‐arc seamount chains. It is suggested that following the opening of the Shikoku back‐arc Basin, Site U1437 was a volcanic front or a rifting zone just behind the volcanic front, and was followed at ~ 9 Ma by the start of rear‐arc seamount chains volcanism. This geochemical change records variations in the subduction components with time, which might have followed eastward moving of hot fingers in the mantle wedge and deepening of the subducting slab below Site U1437 after the cessation of Shikoku back‐arc Basin opening. 相似文献
23.
Alfredo Alberto Muxel Sonia Maria Nobre Gimenez Flaveli Aparecida de Souza Almeida Rení Ventura da Silva Alfaya Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295
The natural cotton fiber was used to synthesize an anion exchange, containing ZrO2 film on its surface, NCFZC (natural cotton fiber/ZrO2 composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model. 相似文献
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新疆博格达造山带北段东侧白杨沟地区分布有大面积的晚石炭世至早二叠世的火山岩,岩石主要由亚碱性玄武岩和安山岩组成,其中分布有大量保存极好的枕状熔岩。枕状熔岩主要为基性熔岩,SiO2含量50.17%~54.66%,Al2O3为13.10%~16.44%,MgO为4.62%~7.89%,TiO2为1.23%~2.79%,CaO为7.06%~13.07%,Na2O为2.76%~4.99%,K2O为0.07%~0.82%。基性熔岩的大离子亲石元素(LILE)一组为富集如Rb和Ba,另一组相对亏损;高场强元素(HFSE)如Nb和Ta在N-MORB标准化图解上都具有明显的负异常。熔岩的稀土元素在球粒陨石标准化配分图解中表现为总体平坦,轻稀土元素(LREE)轻微富集的右倾曲线,δEu为0.89~1.12。从Sr-Nd-Pb同位素组成来看,εNd(t)为+2.8~+3.1,143Nd/144Nd(i)为0.512407~0.512422,εSr(t)为-14.0~-17.5、87Sr/86Sr(i)为0.70293~0.70317、206Pb/204Pb(i)为17.622~17.835、207Pb/204Pb(i)为15.3... 相似文献
27.
利用基本的宝石学方法、紫外可见光分光光度计、红外光谱仪、激光拉曼探针和激光剥蚀等离子质谱技术(LA-ICP-MS)分析了黑龙江穆棱玄武岩风化冲积物中宝石级锆石的宝石学性质、谱学特征、包裹体特征、微量元素组成及U-Pb年龄。宝石学性质表明锆石为优质的、可直接加工利用的宝石原料;谱学特征显示锆石为未经历后期改造的高型岩浆锆石,且含有磷灰石、锆石和赤铁矿包裹体;LA-ICP-MS分析表明锆石具有明显的Ce正异常,富集重稀土元素[(Yb/Sm)N=21~63)]和HFSE元素,Th/U均大于1(1个数据例外);ΣREE较高,含量在1765×10-6~2374×10-6,与基性锆石相似;明显的Ce异常和赤铁矿包裹体说明锆石形成于氧化环境;根据Ti-in-Zircon地质温度计计算,锆石结晶的最低温度为646~737℃;U-Pb年龄为9.39±0.4Ma代表锆石的结晶年龄。基于本实验数据和前人研究成果,认为锆石巨晶形成于富集CO2的氧化环境并且与地幔的交代作用有关,是岩石圈减薄作用发展到一定阶段(衰退期)的产物。 相似文献
28.
为了探讨玄武岩铜矿成矿流体的特征,对滇黔交界地区峨眉山玄武岩铜矿3个成矿期次铜矿石中石英和方解石的气液包裹体进行了激光拉曼成分研究和均一温度、盐度测定,对古石油包裹体通过荧光显微镜进行了成分鉴定。结果表明:第1、2期次成矿流体主要为盆地卤水,其气液包裹体气液比小(一般5%~10%),w(NaCl)为8%~22%,气相为甲烷,液相为水,无子晶及液相CO2,均一温度为80℃~260℃;第2期次成矿流体除盆地卤水外,还有以古石油为代表的有机流体,古石油包裹体由液态烃、固体沥青和气相组成,均一温度变化大(30℃~290℃),液态烃以荧光性强的芳烃为主;第3期次成矿流体具有大气降水成因,其气液包裹体气液比一般为5%~10%,w(NaCl)〈4%,无子晶及液相CO2,均一温度140℃~270℃,但以小于200℃为主。从第1期次到第3期次,成矿流体盐度逐渐降低,特别是第3期次的盐度非常低,但温度变化不明显。本区最重要的自然铜沉淀富集成矿是第2期次不同性质成矿流体混合或成矿流体与有机流体混合、有机质的还原的结果。 相似文献
29.
桂东南沿灵山断裂出露的马山印支期玄武岩的常量元素特征指示它属洋岛碱性玄武岩,微量元素含量显示出大洋板内玄武岩的特点。稀土元素配分型式表现为一组近于平行的向右缓倾曲线,(La/Yb)N=11.69,(Ce/Yb)N=8.64,(Ce/Sm)N=2.41,稀土总量随全碱含量增大有升高的趋势,表明它是亚速尔型洋岛。这首次为桂东南及毗邻的粤西南地区属古特提斯造山带、灵山断裂是古特提斯分支洋盆闭合后的缝合线提供了来自洋盆内地质记录的证据。结合粤桂交界区的最近研究成果提出了研究灵山洋演化的工作模式。 相似文献
30.
Ricardo Arevalo Jr William F. McDonough Philip M. Piccoli 《Geostandards and Geoanalytical Research》2011,35(2):253-273
An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising 43Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 100 μg g?1 and as high as > 104 μg g?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2sm). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials. 相似文献